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NEET • CHEMISTRY • CO-ORDINATION COMPOUNDS
Co-ordination compounds practice · Mixed difficulty
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151
Easy
151 of 320
Remembering
+4 | -1
The ion which exhibits green colour
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Correct option: D
Option D () is correct because ions in aqueous solution typically exhibit a green color due to d-d transitions.
152
Hard
152 of 320
Understanding
+4 | -1
The correct statement among I to III are :
I. Valence bond theory cannot explain the color exhibited by transition metal complexes.
II. Valence bond theory can predict quantitatively the magnetic properties of transition metal complexes.
III. Valence bond theory cannot distinguish ligands as week and strong field ones.
I. Valence bond theory cannot explain the color exhibited by transition metal complexes.
II. Valence bond theory can predict quantitatively the magnetic properties of transition metal complexes.
III. Valence bond theory cannot distinguish ligands as week and strong field ones.
View answer and explanation
Correct option: D
I and III only
Option D (I and III only) is correct because Valence Bond Theory (VBT) fails to explain color and cannot distinguish between weak and strong field ligands.
153
Easy
153 of 320
Remembering
+4 | -1
All ligands are:
View answer and explanation
Correct option: B
Lewis base
Option B is correct because ligands are Lewis bases as they donate electron pairs to the central metal atom to form coordinate bonds.
154
Medium
154 of 320
Understanding
+4 | -1
The correct IUPAC name for is
View answer and explanation
Correct option: C
Iron (III) hexacyanoferrate (II)
Option C (Iron (III) hexacyanoferrate (II)) is correct because it accurately names the compound, indicating the oxidation states of both iron ions.
155
Medium
155 of 320
Remembering
+4 | -1
Strongest field ligand among the following is
View answer and explanation
Correct option: C
Option C is correct because CN- is a strong field ligand according to the spectrochemical series, causing a large crystal field splitting.
156
Medium
156 of 320
Application
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IUPAC name of the given compound is
View answer and explanation
Correct option: B
Potassium trioxalatochromate(III)
Option B (Potassium trioxalatochromate(III)) is correct because it follows the IUPAC naming rules for coordination complexes.
157
Medium
157 of 320
Understanding
+4 | -1
An octahedral complex is formed when central metal atom undergoes hybridization amongst the….orbitals.
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Correct option: D
The correct answer is D () because octahedral complexes involve the hybridization of one s, three p, and two d orbitals.
158
Easy
158 of 320
Application
+4 | -1
A complex compound in which the oxidation number of a metal is zero, is
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Correct option: C
The correct answer is C () because in this complex, the oxidation state of Ni is zero since CO is a neutral ligand.
159
Easy
159 of 320
Understanding
+4 | -1
The type of isomerism shown by the complex is
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Correct option: B
Geometrical isomerism
Option B is correct. The complex exhibits geometrical isomerism because the two chloride ligands and two ethylenediamine ligands can be arranged in cis or trans configurations.
160
Medium
160 of 320
Application
+4 | -1
Atomic numbers of are respectively 24 and 26. Which of the following is paramagnetic with the spin of the electron?
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Correct option: D
Option D ([Cr(NH3)6]3+) is correct because Cr3+ has a d³ configuration, leading to 3 unpaired electrons, making it paramagnetic with a spin.
161
Easy
161 of 320
Application
+4 | -1
In sodium tetrafluorooxochromate(….), the left out place should be filled with which of the following roman numerals?
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Correct option: B
III
Option B (III) is correct because the oxidation state of Cr in the complex must be calculated to balance the charges.
162
Hard
162 of 320
Application
+4 | -1
Which of the following complexes, how many of them are paramagnetic & diamagnetic in nature respectively :-
,
,
Options are :
,
,
Options are :
View answer and explanation
Correct option: C
4, 2
Option C (4, 2) is correct because 4 complexes are paramagnetic and 2 are diamagnetic after determining the electronic configuration and presence of unpaired electrons.
163
Easy
163 of 320
Remembering
+4 | -1
Out of the following the metal which forms polynuclear carbonyl is:
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Correct option: C
Option A () is correct because it represents the correct order of ligand field strength according to the spectrochemical series.
164
Medium
164 of 320
Understanding
+4 | -1
A solution of is used to measure the amount of which gas is a sample by simply measuring change in volume?
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Correct option: C
Option C () is correct because ammoniacal cuprous chloride solution selectively absorbs carbon monoxide.
165
Hard
165 of 320
Understanding
+4 | -1
Why do compounds having similar geometry have different magnetic moment?
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Correct option: C
Due to the presence of weak and strong field ligands
Option C is correct because the presence of weak and strong field ligands affects the electronic configuration and hence the magnetic moment.
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166
Medium
166 of 320
Understanding
+4 | -1
Which one of the following will not show geometrical isomerism?
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Correct option: C
Option C is correct because does not have different spatial arrangements of ligands around the central metal atom.
167
Medium
167 of 320
Analyzing
+4 | -1
Decreasing order of molar conductivity of the following:
(A) (B) (C) (D) will be
(A) (B) (C) (D) will be
View answer and explanation
Correct option: A
Option A () is correct because the molar conductivity decreases with a decrease in the number of ions produced in solution, which corresponds to the number of chloride ions outside the coordination sphere.
168
Easy
168 of 320
Analyzing
+4 | -1
Assertion : On cooling a freezing mixture, colour of the mixture turns to pink from deep blue for a reaction. .
Reason : Reaction is endothermic so on cooling, the reaction moves to backward direction.
Reason : Reaction is endothermic so on cooling, the reaction moves to backward direction.
View answer and explanation
Correct option: A
If both assertion and reason are true and the reason is the correct explanation of the assertion.
The correct answer is A because the reaction is endothermic, and according to Le Chatelier's principle, cooling favors the reverse reaction, shifting the equilibrium towards the reactants and changing the color from blue to pink.
169
Medium
169 of 320
Analyzing
+4 | -1
Among the following metal carbonyls, bond order is lowest in
View answer and explanation
Correct option: B
Option B ([Fe(CO)5]) is correct because a lower positive or higher negative charge on the metal center increases back-bonding, weakening the C-O bond. Since Fe has no charge, it has the lowest backbonding among the negatively and positively charged species.
170
Medium
170 of 320
Application
+4 | -1
Among the following complexes the one which shows zero crystal field stabilization energy (CFSE) is:
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Correct option: B
Option B () is correct because has a configuration, which results in zero CFSE in a weak field.
171
Hard
171 of 320
Analyzing
+4 | -1
Which of the following statement is false
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Correct option: A
Of the species, manganese (III) is strongly reducing while is strongly oxidising.
Option A is false because Mn(III) is easily reduced to Mn(II) and thus is a good oxidizing agent, while Cr(II) is easily oxidized to Cr(III) and is a good reducing agent.
172
Medium
172 of 320
Understanding
+4 | -1
Which of the following is not true for ligand metal complex?
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Correct option: B
Greater the ionization potential of central metal, the stronger is the bond
Option D (Larger the ligand, the more stable is the metal-ligand bond) is not true because larger ligands can cause steric hindrance, which can destabilize the metal-ligand bond.
173
Easy
173 of 320
Understanding
+4 | -1
Which of the following ligand has lowest value?
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Correct option: C
Option C () is correct because fluoride is a weak field ligand and thus has the lowest value.
174
Medium
174 of 320
Understanding
+4 | -1
In which of the following octahedral complexes of (at. No. 27), will be magnitude of be the highest?
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Correct option: A
Option A () is correct because cyanide is a strong field ligand, leading to a large splitting ().
175
Hard
175 of 320
Understanding
+4 | -1
Which of the following complexes are heteroleptic ?
View answer and explanation
Correct option: B
Option B is correct because contains more than one type of ligand coordinated to the central metal ion, making it heteroleptic.
176
Medium
176 of 320
Remembering
+4 | -1
According to spectrochemical series strongest field ligand among the following is
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Correct option: A
Option A is correct because according to the spectrochemical series, NH3 is a stronger field ligand than H2O, F-, and Br-.
177
Easy
177 of 320
Remembering
+4 | -1
cis is used
View answer and explanation
Correct option: C
As anticancer agent
Option C (As anticancer agent) is correct because cis-platin, which is cis-[PtCl(NH)], is a well-known anticancer drug.
178
Hard
178 of 320
Analyzing
+4 | -1
Which one of the following species doesn’t have a magnetic moment of 1.73 BM (spin only value)?
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Correct option: B
Option B () is correct because has in +1 oxidation state, which has a d10 configuration, resulting in no unpaired electrons and hence a magnetic moment of 0 BM.
179
Easy
179 of 320
Understanding
+4 | -1
Colour of transition metal complexes can be explained by:
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Correct option: C
transition
The correct answer is C ( transition) because the color of transition metal complexes arises from the excitation of electrons between orbitals.
180
Medium
180 of 320
Analyzing
+4 | -1
Which of the following statement is correct?
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Correct option: C
can show hydrate isomerism
Option C () is correct because it can exhibit hydrate isomerism, where water molecules can be inside or outside the coordination sphere.
Revision notes and key takeaways
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Showing 151-180 of 320 questions
