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JEE • CHEMISTRY • Equilibrium
Equilibrium practice · Easy
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These sets use single-correct-answer MCQs. They do not cover every JEE Main or JEE Advanced question format and are not full-length mock papers.
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Showing 31-60 of 161 questions
31
Easy
31 of 161
Understanding
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Which of the following pairs constitutes a buffer?
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Correct option: D
and
Option D ( and ) is correct because it consists of a weak acid () and its conjugate base ().
32
Easy
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Understanding
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When sodium acetate is added to an aqueous solution of acetic acid :
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Correct option: B
The of the solution increases
Option B (The pH of the solution increases) is correct because the addition of sodium acetate suppresses the dissociation of acetic acid due to the common ion effect, decreasing [H+] and increasing pH.
33
Easy
33 of 161
Analyzing
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Which of the following salts will give highest in water
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Correct option: C
The correct answer is C () because it is a salt of a strong base (NaOH) and a weak acid (), resulting in a higher pH due to hydrolysis.
34
Easy
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Understanding
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The reaction is reversible if it is carried out
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Correct option: D
In a closed vessel
Option D is correct because for a reaction to be reversible, it must be carried out in a closed vessel to prevent the escape of gaseous products, allowing the reverse reaction to occur.
35
Easy
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Understanding
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Which of these is a Lewis acid?
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Correct option: A
Option A () is correct because aluminum chloride is electron deficient and can accept a lone pair of electrons.
36
Easy
36 of 161
Analyzing
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Among which one will be the best Lewis acid?
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Correct option: A
Option A () is the best Lewis acid because it has the least back bonding due to the larger size of Cl compared to F, making it more electron deficient.
37
Easy
37 of 161
Application
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What is the minimum necessary to cause a precipitate of to form in a solution ?
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Correct option: C
12
Option C (12) is correct because it is the minimum pH required to precipitate Pb(OH)₂ from a 0.12 M PbCl₂ solution, calculated using the Ksp value.
38
Easy
38 of 161
Analyzing
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STATEMENT-1 : The endothermic reactions are favoured at lower temperature and the exothermic reactions are favoured at higher temperature.
STATEMENT-2 : When a system in equilibrium is disturbed by changing the temperature, it will tend to adjust itself so as to overcome the effect of change
STATEMENT-2 : When a system in equilibrium is disturbed by changing the temperature, it will tend to adjust itself so as to overcome the effect of change
View answer and explanation
Correct option: D
If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE
Option D is correct because statement 1 is false as endothermic reactions are favored at higher temperatures, and statement 2 is true, reflecting Le Chatelier's principle.
39
Easy
39 of 161
Application
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In of an aqueous of of distilled water is added, the pH of the resultant solution becomes:
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Correct option: B
Option B (2.0) is correct because diluting the HCl solution decreases the concentration of H+ ions, resulting in a pH increase from 1.0 to 2.0.
40
Easy
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Application
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Solution prepared by dissolving equal number of mole of and is a buffer of pH:
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Correct option: B
Option A () is correct because when the concentration of the acid and its conjugate base are equal, the pH equals the pKa of the acid.
41
Easy
41 of 161
Understanding
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Which one of the molecular hydride acts as Lewis acid?
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Correct option: C
Option C () is correct because diborane is an electron-deficient compound and acts as a Lewis acid by accepting electron pairs.
42
Easy
42 of 161
Remembering
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Which of the following mixture is a buffer solution?
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Correct option: D
Option D () is correct because a buffer solution consists of a weak acid/base and its conjugate salt, and this option represents a weak base (ammonium hydroxide) and its salt (ammonium chloride).
43
Easy
43 of 161
Remembering
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Which of the following is Lewis acid?
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Correct option: B
Option B () is correct because Lewis acids are electron-deficient species, and can accept an electron pair.
44
Easy
44 of 161
Understanding
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For an equilibrium which of the following statements is true:
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Correct option: B
More of ice melts if pressure on the system is increased
The correct answer is B (More of ice melts if pressure on the system is increased) because increasing pressure favors the liquid phase, which has a smaller volume than the solid phase.
45
Easy
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Analyzing
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Assertion : of hydrochloric acid solution is less than that of acetic acid solution of the same concentration.
Reason : In equimolar solutions, the number of titrable protons present in hydrochloric acid is less than that persent in acetic acid.
Reason : In equimolar solutions, the number of titrable protons present in hydrochloric acid is less than that persent in acetic acid.
View answer and explanation
Correct option: C
If assertion is true but reason is false.
Hydrochloric acid (HCl) is a strong acid and completely dissociates in solution, resulting in a lower pH compared to acetic acid (CH3COOH), which is a weak acid. The number of titratable protons is not less in HCl. Therefore, the assertion is true, but the reason is false, making option C the correct answer.
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46
Easy
46 of 161
Analyzing
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The equilibrium constants of the following are.
The equilibrium constant of the reaction
will be
The equilibrium constant of the reaction
will be
View answer and explanation
Correct option: C
Option C is correct. The equilibrium constant K is calculated by combining the given reactions to match the target reaction and then multiplying/dividing the corresponding equilibrium constants.
47
Easy
47 of 161
Remembering
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The pH of solution, whose hydrogen ion concentration is one mole per litre, will be:
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Correct option: C
Zero
Option C (Zero) is correct because the pH is calculated as the negative logarithm of the hydrogen ion concentration, and the negative logarithm of 1 is 0.
48
Easy
48 of 161
Application
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The rate constant for forward reaction and backward reaction of hydrolysis of ester are and per minute respectively. Equilibrium constant for the reaction is
View answer and explanation
Correct option: B
Option B (7.33) is correct because the equilibrium constant is the ratio of the forward rate constant to the backward rate constant.
49
Easy
49 of 161
Understanding
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Which of the following is a Bronsted acid as well as Bronsted base:
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Correct option: B
Option B () is correct because water can act as both a proton donor (acid) and a proton acceptor (base).
50
Easy
50 of 161
Understanding
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Unit of equilibrium constant for the reversible reaction is
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Correct option: D
None of these
Option D (None of these) is correct because for the reaction , the change in the number of moles is zero, so the equilibrium constant is dimensionless.
51
Easy
51 of 161
Application
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pH of a solution is
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Correct option: A
Option A (4.0) is correct because the pH is calculated directly from the hydrogen ion concentration: pH = -log[H+].
52
Easy
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Understanding
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If acetic acid is mixed with sodium acetate then ion concentration will
View answer and explanation
Correct option: B
Decrease
Option B (Decrease) is correct because adding sodium acetate, a common ion, to acetic acid will shift the equilibrium to the left, decreasing the hydrogen ion concentration due to the common ion effect.
53
Easy
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Analyzing
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Assertion(A) is a Lewis acid as well as Bronsted-Lowry acid.
Reason(R) Any species which can accept a lone pair of electrons is a Lewis acid and the species that can lose a proton is Bronsted-Lowry acid.
Reason(R) Any species which can accept a lone pair of electrons is a Lewis acid and the species that can lose a proton is Bronsted-Lowry acid.
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Correct option: D
If is incorrect but (R) is correct.
The correct answer is D (If is incorrect but (R) is correct) because is a Lewis acid but not a Bronsted-Lowry acid, while the reason correctly defines Lewis and Bronsted-Lowry acids.
54
Easy
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Application
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Maximum possible of a solution of slaked lime is of :
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Correct option: D
Option D (12.6) is correct because it is calculated from the solubility product of calcium hydroxide, considering the hydroxide ion concentration and then calculating the pH.
55
Easy
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Application
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Given the reaction between 2 gases represented by and to give the compound
At equilibrium, the concentration
of
of
of
If the reaction takes place in a sealed vessel at , then the value of will be :
At equilibrium, the concentration
of
of
of
If the reaction takes place in a sealed vessel at , then the value of will be :
View answer and explanation
Correct option: C
The correct answer is 0.62 (Option C) because it is calculated by substituting the given equilibrium concentrations into the equilibrium constant expression, .
56
Easy
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Application
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For the reaction , the value of at is What is the value of at this temperature?
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Correct option: D
0.1
Option D (0.1) is correct because for this reaction, Kp equals Kc since the change in moles of gas is zero.
57
Easy
57 of 161
Understanding
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On doubling and with constant temperature the equilibrium constant will
View answer and explanation
Correct option: A
Remain constant
Option A (Remain constant) is correct because the equilibrium constant (K) is only affected by changes in temperature, not pressure or volume.
58
Easy
58 of 161
Analyzing
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Which one of the following statements is not true?
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Correct option: C
The pH of is 8
Option C is not true. The pH of is not 8 because the solution is acidic. You must also consider the autoionization of water. The pH will be slightly less than 7.
59
Easy
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Application
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At a given temperature the for the reaction, is . At the same temperature, the for the reaction
is :
is :
View answer and explanation
Correct option: C
The correct answer is C () because the equilibrium constant for the reverse reaction is the inverse of the equilibrium constant for the forward reaction.
60
Easy
60 of 161
Understanding
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For which reaction Kp � Kc ?
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Correct option: D
Option D () is correct because � when Δn � 0, and in this reaction, Δn = 2 - 1 = 1.
Revision notes and key takeaways
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