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JEE • CHEMISTRY • ALCOHOLS & PHENOLS & ETHERS
Alcohols & phenols & ethers practice · Mixed difficulty
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These sets use single-correct-answer MCQs. They do not cover every JEE Main or JEE Advanced question format and are not full-length mock papers.
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Showing 31-60 of 193 questions
31
Medium
31 of 193
Analyzing
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Assertion: Phenol undergo Kolbe reaction, ethanol does not.
Reason: Phenoxide ion is more basic than ethoxide ion.
Reason: Phenoxide ion is more basic than ethoxide ion.
View answer and explanation
Correct option: C
If Assertion is correct but Reason is incorrect.
Option C is correct. The assertion is correct as phenol undergoes Kolbe reaction while ethanol does not, but the reason is incorrect because phenoxide ion is less basic than ethoxide ion.
32
Easy
32 of 193
Understanding
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If methanol vapour is passed over heated copper at , it forms formaldehyde by:
View answer and explanation
Correct option: B
Dehydrogenation
Option B (Dehydrogenation) is correct because methanol is converted to formaldehyde by the removal of hydrogen atoms.
33
Medium
33 of 193
Remembering
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Anisole is the product obtained from phenol by the reaction known as
View answer and explanation
Correct option: B
Etherification
Option B (Etherification) is correct because anisole is a phenolic ether formed by the reaction of phenol with an alkyl halide or alcohol.
34
Hard
34 of 193
Analyzing
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Assertion: Addition of water to but-1-ene in acidic medium yields butan-1-ol.
Reason: Addition the formation of primary carbocation.
Reason: Addition the formation of primary carbocation.
View answer and explanation
Correct option: D
If both Assertion and Reason are false
Option D (If both Assertion and Reason are false) is correct because the addition of water to but-1-ene in acidic medium yields butan-2-ol, not butan-1-ol, and the reaction proceeds via a secondary carbocation.
35
Medium
35 of 193
Remembering
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Esterification of alcohols involves:
View answer and explanation
Correct option: A
of alcohol and of acid
Option A ( of alcohol and of acid) is correct because esterification involves the removal of from the alcohol and from the carboxylic acid to form water.
36
Medium
36 of 193
Analyzing
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How many structural isomers are known for ?
View answer and explanation
Correct option: D
7
The correct answer is D (7) because there are 4 alcohol isomers and 3 ether isomers possible for the molecular formula C4H10O.
37
Easy
37 of 193
Remembering
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Phenol gives characteristic colouration with
View answer and explanation
Correct option: C
Aqueous solution
Option C (Aqueous solution) is correct because phenol gives a characteristic color with ferric chloride solution.
38
Medium
38 of 193
Understanding
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Which of the following alcohol gives an alkyl halide on simply shaking with at room temperature?
View answer and explanation
Correct option: A
Option A () is correct because tertiary alcohols react fastest with HCl due to the formation of a stable tertiary carbocation intermediate.
39
Medium
39 of 193
Understanding
+4 | -1
When ethyl alcohol is dissolved in water, it is accompanied with:
View answer and explanation
Correct option: C
Absorption of heat and increase in volume
Option C (Absorption of heat and increase in volume) is correct because when ethyl alcohol is dissolved in water, it leads to an increase in volume and absorption of heat, indicating a positive deviation from Raoult's law.
40
Medium
40 of 193
Understanding
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Alcoholic fermentation of sugar gives 3% glycerol. The yield can be increased to 25% if fermentation is made in presence of:
View answer and explanation
Correct option: C
Option D (None of these) is correct because the presence of sodium bisulfite () increases the glycerol yield during alcoholic fermentation, not the given options.
41
Easy
41 of 193
Application
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Which compound is formed when sodium phenoxide is heated with ethyl iodide?
View answer and explanation
Correct option: A
Phenetole
Option A (Phenetole) is correct because the reaction of sodium phenoxide with ethyl iodide results in the formation of phenetole via Williamson ether synthesis.
42
Medium
42 of 193
Remembering
+4 | -1
Alkyd resins, made of glycerol are used:
View answer and explanation
Correct option: C
For paints and coatings
Option C (For paints and coatings) is correct because alkyd resins, made from glycerol, are widely used in the production of paints and coatings due to their film-forming properties.
43
Easy
43 of 193
Understanding
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The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is
View answer and explanation
Correct option: B
Option B () is correct because the ease of dehydrohalogenation follows the stability of the alkene formed, with tertiary alkyl halides forming more substituted and stable alkenes.
44
Medium
44 of 193
Understanding
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An aqueous solution of ethyl alcohol:
View answer and explanation
Correct option: C
Does not affect the litmus colour
Option C (Does not affect the litmus colour) is correct because ethyl alcohol is a neutral compound and does not change the pH of the solution.
45
Medium
45 of 193
Analyzing
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An alcohol is not oxidised in alkaline or neutral solution but in acidic solution it is turned first to acetone and then to acetic acid. It is a:
View answer and explanation
Correct option: C
Tertiary alcohol
Tertiary alcohols are not easily oxidized in alkaline or neutral solutions. In acidic conditions, they can be converted to alkenes and then further oxidized.
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46
Easy
46 of 193
Understanding
+4 | -1
When acetyl chloride is reduced with , the product formed is:
View answer and explanation
Correct option: B
Ethyl alcohol
Option B (Ethyl alcohol) is correct because the reduction of acetyl chloride with results in the formation of a primary alcohol, which is ethyl alcohol.
47
Medium
47 of 193
Application
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2 mole of ethanol are burnt. The amount of obtained will be:
View answer and explanation
Correct option: C
176 g
Option C (176 g) is correct because 2 moles of ethanol produce 4 moles of CO2, and the molar mass of CO2 is 44 g/mol, so 4 * 44 = 176 g.
48
Medium
48 of 193
Understanding
+4 | -1
Increasing order of acid strength among methoxyphenol, methylphenol and nitrophenol is:
View answer and explanation
Correct option: B
methoxyphenol methylphenol nitrophenol
Option B (methoxyphenol methylphenol nitrophenol) is correct because electron-donating groups like methoxy decrease acidity, while electron-withdrawing groups like nitro increase acidity.
49
Hard
49 of 193
Analyzing
+4 | -1
Which of the following ethers is the most unreactive to cleavage with ?
View answer and explanation
Correct option: C
Option C () is the most unreactive because the oxygen's lone pairs are delocalized into both phenyl rings, stabilizing the ether and making it less susceptible to cleavage.
50
Medium
50 of 193
Analyzing
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Which is true about this reaction?
View answer and explanation
Correct option: A
is meso 2,3-butan-di-ol formed by syn addition
Option A (A is meso 2,3-butan-di-ol formed by syn addition) is correct because the syn addition of two -OH groups to a cis-alkene results in the formation of a meso compound.
51
Easy
51 of 193
Understanding
+4 | -1
Assertion: Methanol is called wood spirit.
Reason: Methanol can be prepared by the destructive distillation of fresh wood.
Reason: Methanol can be prepared by the destructive distillation of fresh wood.
View answer and explanation
Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
The correct answer is A (Both assertion and reason are correct statements, and reason is the correct explanation of the assertion) because methanol is indeed called wood spirit and it can be prepared by the destructive distillation of wood.
52
Hard
52 of 193
Remembering
+4 | -1
Nobel’s oil is:
View answer and explanation
Correct option: C
Explosive
Option C (Explosive) is correct because Nobel's oil is another name for nitroglycerin, a powerful explosive.
53
Easy
53 of 193
Understanding
+4 | -1
Among the following compounds, the strongest acid is:
View answer and explanation
Correct option: D
Option D () is the strongest acid among the given compounds because oxygen is more electronegative than carbon, leading to a more polar and easily ionizable O-H bond.
54
Medium
54 of 193
Analyzing
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Assertion : Reimer-Tiemann reaction of phenol with in at gives salicyclic acid as the major product.
Reason: The reaction occurs through intermediate formation of dichlorocarbene.
Reason: The reaction occurs through intermediate formation of dichlorocarbene.
View answer and explanation
Correct option: C
Assertion is correct, reason is incorrect.
Option C is correct. The assertion is correct as Reimer-Tiemann reaction with CCl4 gives salicylic acid, but the reason is incorrect as the intermediate is dichlorocarbene.
55
Medium
55 of 193
Remembering
+4 | -1
Terylene is formed by the reaction of one of the following alcohols:
View answer and explanation
Correct option: C
Ethanediol
Option C (Ethanediol) is correct because Terylene (Dacron) is a polyester formed by the polymerization of ethylene glycol (ethanediol) and terephthalic acid.
56
Easy
56 of 193
Remembering
+4 | -1
Bisphenol A is
View answer and explanation
Correct option: C
Phenol + Acetone
Option C (Phenol + Acetone) is correct because Bisphenol A is synthesized from Phenol and Acetone.
57
Medium
57 of 193
Analyzing
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An organic compound on treatment with PCC in dichloromethane gives the compound Compound reacts with and alkali to form yellow precipitate of triiodomethane. The compound is
View answer and explanation
Correct option: C
Option C () is correct because it's the only alcohol that can be oxidized to an aldehyde that gives a positive iodoform test.
58
Medium
58 of 193
Understanding
+4 | -1
Which one of the following compounds will not react with ?
View answer and explanation
Correct option: C
Dimethyl ether
Option C (Dimethyl ether) is correct because Grignard reagents react with compounds containing acidic hydrogens or carbonyl groups, which are absent in dimethyl ether.
59
Medium
59 of 193
Understanding
+4 | -1
Which of the following statements are correct?
(i) In phenols, the group is attached to hybridised carbon of an aromatic ring
(ii) The carbon - oxygen bond length (136 pm) in phenol is slightly more than that in methanol
(iii) Partial double bond character is due to the conjugation of unshared electron pair of oxygen with the aromatic ring.
(iv) hybridised state of carbon to which oxygen is attached.
(i) In phenols, the group is attached to hybridised carbon of an aromatic ring
(ii) The carbon - oxygen bond length (136 pm) in phenol is slightly more than that in methanol
(iii) Partial double bond character is due to the conjugation of unshared electron pair of oxygen with the aromatic ring.
(iv) hybridised state of carbon to which oxygen is attached.
View answer and explanation
Correct option: C
(i), (iii) and (iv)
The correct answer is C () because the difference between and at constant volume is .
60
Easy
60 of 193
Understanding
+4 | -1
The compound is converted into by:
View answer and explanation
Correct option: D
Substitution
Option D (Substitution) is correct because the bromine atom in is replaced by a hydroxyl group (OH) to form .
Revision notes and key takeaways
Review ALCOHOLS & PHENOLS & ETHERS in your textbook or class notes, then use this set to check your understanding.
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