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JEE CHEMISTRY MCQ: REDOX REACTIONS

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Given:

E12Cl2/Clāˆ’o=1.36Ā V,ECr3+/Cro=āˆ’0.74Ā V,ECr2O72āˆ’/Cr3+o=1.33Ā V,EMnO4āˆ’/Mn2+o=1.51Ā V\begin{aligned} & {E}_{\frac{1}{2} {Cl}_2 / {Cl}^{-}}^{{o}}=1.36 {~V}, {E}_{{Cr}^{3+} / {Cr}}^{{o}}=-0.74 {~V}, \\ & {E}_{{Cr}_2 {O}_7^{2-} / {Cr}^{3+}}^{{o}}=1.33 {~V}, {E}_{{MnO}_4^{-} / {Mn}^{2+}}^{{o}}=1.51 {~V} \end{aligned}

The correct order of reducing power of the species (Cr,Cr3+,Mn2+\left({Cr}, {Cr}^{3+}, {Mn}^{2+}\right. and Clāˆ’)\left.{Cl}^{-}\right)will be
View answer and explanation
Correct option: A
Mn2+<Clāˆ’<Cr3+<Cr{Mn}^{2+}<{Cl}^{-}<{Cr}^{3+}<{Cr}
The correct answer is A (Mn2+<Clāˆ’<Cr3+<Cr{Mn}^{2+}<{Cl}^{-}<{Cr}^{3+}<{Cr}) because the reducing power increases as the reduction potential decreases.

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