JEE CHEMISTRY MCQ: Equilibrium

1 Medium

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Analyzing +4 | -1

Assertion :- Addition of

{NH}_4 {OH}

to an aqueous solution of

{BaCl}_2

in the presence of

{NH}_4 {Cl}

(excess) precipitates

{Ba}({OH})_2.

Reason :-

{Ba}({OH})_2

is insoluble in water.

View answer and explanation

Correct option: D

If both Assertion & Reason are False

Option D (If both Assertion & Reason are False) is correct because the assertion is false as Ba(OH)2 doesn't precipitate in the presence of NH4Cl and NH4OH, and the reason is false because Ba(OH)2 is soluble in water.

More Questions from Equilibrium

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The indicator used in titrating oxalic acid with caustic soda solution is:

\mathrm{K}_1

and

\mathrm{K}_2

are equilibrium constant for reactions (i) and (ii)

\mathrm{N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})\quad\ldots

(i)

\mathrm{NO}(\mathrm{g}) \rightleftharpoons \frac{1}{2} \mathrm{~N}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})\quad\ldots

(ii)

Then,

K{a_1},\,\,\,K{a_2}\,\,\,\mathrm{and}\,\,\,K{a_3}

are the respective ionisation constants for the following reactions

\begin{array}{l} {H_2}S\leftrightharpoons{H^ + } + H{S^ - }\\ H{S^ - }\leftrightharpoons{H^ + } + {S^{2 - }}\\ {H_2}S\leftrightharpoons2{H^ + } + {S^{2 - }} \end{array}

The correct relationship between

K{a_1},\,\,K{a_2}\,,K{a_3}

is The

\mathrm{pH}

0.1 \mathrm{~M}-\mathrm{N}_2 \mathrm{H}_4

solution is (For

\mathrm{N}_2 \mathrm{H}_4,

K_{{b}_1}=3.6 \times 10^{-6}, K_{{b}_2}=6.4 \times 10^{-12}, \log 2=0.3

\log 3=0.48

) Reaction

{\text{Ba}}{{\text{O}}_2}(s) \rightleftharpoons {\text{BaO}}(s) + {{\text{O}}_2}(g);\Delta H = - {\text{ve}}.

In equilibrium condition pressure of

\text{O}_2

depends on: A : At equilibrium concentration of the reactant and product does not change with time for a chemical reaction.
R: The rate of reaction is zero at equilibrium.