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NEET UG CHEMISTRY MCQ: SOME BASIC CONCEPTS OF CHEMISTRY

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A mixture of NaHC2O4\mathrm{NaHC}_2 \mathrm{O}_4 and KHC2O4⋅H2C2O4\mathrm{KHC}_2 \mathrm{O}_4 \cdot \mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4 required equal volumes of 0.2 N KMnO40.2 \mathrm{~N} \mathrm{~KMnO}_4 and 0.12 NNaOH0.12 \mathrm{~N} \mathrm{NaOH} separately. What is the molar ratio of NaHC2O4\mathrm{NaHC}_2 \mathrm{O}_4 and KHC2O4⋅H2C2O4\mathrm{KHC}_2 \mathrm{O}_4 \cdot \mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4 in the mixture?
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Correct option: D
3:13: 1
Option D is correct because the molar ratio of NaHC2O4 to KHC2O4.H2C2O4 is 3:1, calculated by equating the equivalents of KMnO4 and NaOH used in the titrations.

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