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JEE CHEMISTRY MCQ: ALCOHOLS & PHENOLS & ETHERS

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Analyzing +4 | -1
Rank the following substances in order of increasing boiling point (Lowest β†’\to Highest).
a.   CH3CH2CH2CH2OHb.   (CH3)2CHOCH3c.   (CH3)3COHd.   (CH3)4C\begin{array}{cccccccccccccccccccc} {{\text{a}}{\text{.}}\,\,\,C{H_3}C{H_2}C{H_2}C{H_2}OH}&{{\text{b}}{\text{.}}\,\,\,{{\left( {C{H_3}} \right)}_2}CHOC{H_3}}&{{\text{c}}{\text{.}}\,\,\,{{\left( {C{H_3}} \right)}_3}COH}&{{\text{d}}{\text{.}}\,\,\,{{\left( {C{H_3}} \right)}_4}C} \end{array}
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Correct option: C
d < b < c < a
Option C (d < b < c < a) is correct because boiling point increases with increasing molecular weight and hydrogen bonding, and decreases with branching.

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