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JEE CHEMISTRY MCQ: CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

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Assertion (A): Na+\mathrm{Na}^{+} and Al3+\mathrm{Al}^{3+} are isoelectronic but the ionic radii of Al3+\mathrm{Al}^{3+} is smaller than Na+\mathrm{Na}^{+}
Reason (R): The nuclear attraction on the outermost shell electrons of Al3+\mathrm{Al}^{3+} is greater than that of Na+\mathrm{Na}^{+}.
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Correct option: A
Both Assertion and Reason are correct; Reason is the correct explanation of Assertion
Option A (Both Assertion and Reason are correct; Reason is the correct explanation of Assertion) is correct because both ions are isoelectronic, and the higher nuclear charge of Al³⁺ results in a smaller ionic radius.

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