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JEE CHEMISTRY MCQ: THERMODYNAMICS

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Analyzing +4 | -1
Assertion : Many endothermic reactions that are not spontaneous at room temperature become spontaneous at high temperature.
Reason : Entropy of the system increases with increase in temperature.
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Correct option: B
If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.
Option B (If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion) is correct because both the assertion and the reason are true, but the increase in entropy is not the direct cause of endothermic reactions becoming spontaneous at high temperatures.

More Questions from THERMODYNAMICS

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Consider following reactions
I:  C(s)+12O2( g)−CO(g),ΔH1=a\ \mathrm{C}(\mathrm{s})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})-\mathrm{CO}(\mathrm{g}), \Delta \mathrm{H}_1=\mathrm{a}

II: CO(g)+12O2( g)−CO2( g),ΔH2=b\mathrm{CO}(\mathrm{g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})-\mathrm{CO}_2(\mathrm{~g}), \Delta \mathrm{H}_2=\mathrm{b}

III: C(s)+CO2( g)−2CO(g);ΔH3=c\mathrm{C}(\mathrm{s})+\mathrm{CO}_2(\mathrm{~g})-2 \mathrm{CO}(\mathrm{g}) ; \Delta \mathrm{H}_3=\mathrm{c}
Select the correct statement
When 0.18 g0.18 \mathrm{~g} of glucose was burnt in a bomb calorimeter, the temperature rose by 4 K.4 \mathrm{~K}. The heat capacity of the calorimeter system is (ΔCH∘=−2.8×106 J/mol glucose)\left(\Delta_{\mathrm{C}} \text{H}^{\circ}=-2.8\times 10^6 \mathrm{~J} / \mathrm{mol} \text{ glucose}\right) Statement-1: CsI{CsI} is less soluble in water compared to CsCl{CsCl}
Satement-2: More amount of heat is liberated during the formation of CsCl{CsCl} than the formation CsI{Cs} I from their elements
Consider the following processes :

ΔH(KJ/mol)1/2A→B+1503B→2C+D−125E+A→2D+350\begin{array}{cccccccccccccccccccc} {}&{\Delta H(KJ/mol)} \\ {1/2A \to B}&{ + 150} \\ {3B \to 2C + D}&{ - 125} \\ {E + A \to 2D}&{ + 350} \end{array}

For B+D→E+2C,ΔH{B}+{D} \rightarrow {E}+2 {C}, \Delta {H} will be :
The difference b/w ΔH\Delta H and Δu\Delta u at constant volume is equal to The heat evolved in the combustion of methane is given by the following equations CH4(g)+2O2(g)→CO2(g)+H2O(l);ΔH=−890.3kJ\mathrm{C}{\mathrm{H}_4}\left( \mathrm{g} \right) + 2{\mathrm{O}_2}\left( \mathrm{g} \right) \to \mathrm{C}{\mathrm{O}_2}\left( \mathrm{g} \right) + {\mathrm{H}_2}\mathrm{O}\left( l \right);\Delta H = - 890.3\mathrm{kJ} How many grams of methane would be required to produce 44.15 kJ of heat of combustion?
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