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NEET UG CHEMISTRY MCQ: ALDEHYDES & KETONES & CARBOXYLIC ACIDS

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A compound ‘A’ having the molecular formula C5H12O{\mathrm{C}_5}{\mathrm{H}_{12}}\mathrm{O}, on oxidation gives a compound ‘B’with molecular formula C5H12O{\mathrm{C}_5}{\mathrm{H}_{12}}\mathrm{O}. Compound ‘B’ gave a 2, 4-dinitrophenylhydrazine derivative but did not answer haloform test or silver mirror test. The structure of compound ‘A’
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Correct option: C
CH3−CH2−CH−CH2−CH3                                            ∣                                      OH\begin{array}{l} \mathrm{C}{\mathrm{H}_3} - \mathrm{C}{\mathrm{H}_2} - \mathrm{CH} - \mathrm{C}{\mathrm{H}_2} - \mathrm{C}{\mathrm{H}_3}\\ \;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;|\\ \;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;\;OH \end{array}
Option C is correct because the compound 'A' is a secondary alcohol that gets oxidized to a ketone, which gives a positive 2,4-DNP test but negative haloform and silver mirror tests.

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