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JEE CHEMISTRY MCQ: HALOALKANES AND HALO ARENES

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Arrange the following in the increasing order of ease of dehydrohalogenation
CH3CH2Cl,CH3CH(Cl)CH3,(CH3)3CCl\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Cl}, \mathrm{CH}_3 \mathrm{CH}(\mathrm{Cl}) \mathrm{CH}_3,\left(\mathrm{CH}_3\right)_3 \mathrm{CCl}
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Correct option: A
CH3CH2Cl<CH3CH(Cl)CH3<(CH3)3CCl\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Cl} < \mathrm{CH}_3 \mathrm{CH}(\mathrm{Cl}) \mathrm{CH}_3 < \left(\mathrm{CH}_3\right)_3 \mathrm{CCl}
Option A (CH3CH2Cl<CH3CH(Cl)CH3<(CH3)3CCl\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Cl} < \mathrm{CH}_3 \mathrm{CH}(\mathrm{Cl}) \mathrm{CH}_3 < (\mathrm{CH}_3)_3 \mathrm{CCl}) is correct because the ease of dehydrohalogenation follows the stability of the carbocation formed, which is tertiary > secondary > primary.

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