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NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Analyzing +4 | -1
250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO30.1\,M\,AgN{O_3} and 0.1 M AgCl.0.1\,M\,AgCl. The solution was electrolyzed at 2 V by passing a current of 1 A for 15 minutes. The metal/metals electro deposited will be:
(EAg+/Ag0=0.80 V,EAu+/Au0 =1.69 V)\left( {E_{A{g^ + }/Ag}^0 = 0.80\,V,E_{A{u^ + }/Au}^0\, = 1.69\,V} \right)
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Correct option: A
Only gold
Option A (Only gold) is correct because gold has a higher reduction potential than silver, meaning silver will deposit first, and the applied voltage is sufficient to deposit gold.

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