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NEET UG CHEMISTRY MCQ: SOLID STATE

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The melting point of RbBr\mathrm{RbBr} is 682∘C\mathrm{682}^\circ \mathrm{C}, while that of NaF\mathrm{NaF} is 988∘C\mathrm{988}^\circ \mathrm{C}. The principle reason that melting point of NaF\mathrm{NaF} is much higher than that of RbBr\mathrm{RbBr} is that :
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Correct option: C
The internuclear distance rc+ra{r_\mathrm{c}} + {r_\mathrm{a}} is greater for RbBr\mathrm{RbBr} than for NaF\mathrm{NaF}
Option C (The internuclear distance rc+ra{r_\mathrm{c}} + {r_\mathrm{a}} is greater for RbBr\mathrm{RbBr} than for NaF\mathrm{NaF}) is correct because a smaller internuclear distance in NaF leads to stronger electrostatic forces and thus a higher melting point.

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