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JEE CHEMISTRY MCQ: STATES OF MATTER

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Analyzing +4 | -1
0.5 mole of each of H2,SO2{\mathrm{H}_2},\mathrm{S}{\mathrm{O}_2} and CH4\mathrm{C}{\mathrm{H}_4} are kept in a container. A hole was made in the container. After 3 h, the order of partial pressures in the container will be
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Correct option: B
pSO2>pCH4>pH2p\mathrm{S}{\mathrm{O}_2} > p\mathrm{C}{\mathrm{H}_4} > p{\mathrm{H}_2}
Option B (pSO2>pCH4>pH2p\mathrm{S}{\mathrm{O}_2} > p\mathrm{C}{\mathrm{H}_4} > p{\mathrm{H}_2}) is correct because the rate of diffusion is inversely proportional to the square root of the molecular mass. Therefore, the gas with the highest molecular mass will have the lowest diffusion rate and hence the highest partial pressure after 3 hours.

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