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NEET UG CHEMISTRY MCQ: STATES OF MATTER

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Amongst NH3,PH3,AsH3N{H_3},P{H_3},As{H_3} and SbH3Sb{H_3} the one with highest B.P is
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Correct option: B
SbH3Sb{H_3} because of higher molecular weight
Option B (SbH3Sb{H_3} because of higher molecular weight) is correct because as the molecular weight increases down the group, the strength of the London dispersion forces increases, leading to a higher boiling point. NH3NH_3 has hydrogen bonding which would normally make it have the highest boiling point, but SbH3 has a significantly higher molecular weight which overcomes the hydrogen bonding in NH3.

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