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NEET UG CHEMISTRY MCQ: SOLUTIONS
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Camphor is used as solvent to determine mol. wt. of non-volatile solute by Rast method because for camphor :
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Correct option: C
Molal depression constant is high
Camphor has a high molal depression constant, which leads to a significant depression in freezing point even for small amounts of solute, making option C the correct answer. This makes it suitable for determining the molecular weight of non-volatile solutes using the Rast method.
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Reason: Isotonic solutions have equal osmotic pressure at constant temperature. 0.2 molal aqueous solution of a monobasic acid is 60% ionised. If Kb for water is then the boiling point of the solution will be The vapour pressures of pure liquids and are 400 and 600 mmHg, respectively at 298 K. On mixing the two liquids, the sum of their initial volumes is equal to the volume of the final mixture. The mole fraction of liquid is 0.5 in the mixture. The vapour pressure of the final solution, the mole fractions of components and in vapour phase, respectively are What is molecular weight of a substance whose 7.0% by mass solution in water freezes at . for water is A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. the vapour pressure of propyl alcohol is 200 mm. If the mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm) at the same temperature will be
Reason: Isotonic solutions have equal osmotic pressure at constant temperature. 0.2 molal aqueous solution of a monobasic acid is 60% ionised. If Kb for water is then the boiling point of the solution will be The vapour pressures of pure liquids and are 400 and 600 mmHg, respectively at 298 K. On mixing the two liquids, the sum of their initial volumes is equal to the volume of the final mixture. The mole fraction of liquid is 0.5 in the mixture. The vapour pressure of the final solution, the mole fractions of components and in vapour phase, respectively are What is molecular weight of a substance whose 7.0% by mass solution in water freezes at . for water is A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. the vapour pressure of propyl alcohol is 200 mm. If the mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm) at the same temperature will be