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JEE CHEMISTRY MCQ: HALOALKANES AND HALO ARENES

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Aryl halides can not be prepared by the reaction of aryl alcohols with PCl3,PCl5{PCl}_3, {PCl}_5 or SOCl2{SOCl}_2 because
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Correct option: B
Carbon-oxygen bond in phenols has a partial double bond character.
Option B (Carbon-oxygen bond in phenols has a partial double bond character) is correct because the resonance in aryl alcohols (phenols) gives the C-O bond a partial double bond character, making it stronger and harder to break.

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