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JEE CHEMISTRY MCQ: CHEMICAL BONDING & MOLECULAR STRUCTURE

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Assertion (A): The order of thermal stability of

Li2CO3<Na2CO3<K2CO3<Rb2CO3<Cs2CO3\mathrm{Li}_2 \mathrm{CO}_3< \mathrm{Na}_2 \mathrm{CO}_3< \mathrm{K}_2 \mathrm{CO}_3< \mathrm{Rb}_2 \mathrm{CO}_3< \mathrm{Cs}_2 \mathrm{CO}_3

Reason (R): As we go

Li2CO3β†’Na2CO3β†’Β K2CO3β†’Rb2CO3β†’Cs2CO3\mathrm{Li}_2 \mathrm{CO}_3 \rightarrow \mathrm{Na}_2 \mathrm{CO}_3 \rightarrow \mathrm{~K}_2 \mathrm{CO}_3 \rightarrow \mathrm{Rb}_2 \mathrm{CO}_3 \rightarrow \mathrm{Cs}_2 \mathrm{CO}_3

ionic character of carbonates increases.
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Correct option: A
Both (A) & (R) are true and the (R) is the correct explanation of the (A)
Option A is correct because both the assertion and the reason are true, and the reason correctly explains the assertion regarding the thermal stability of alkali metal carbonates.

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