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JEE CHEMISTRY MCQ: CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

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The formation of O2−(g){O}^{2-}(\mathrm{g}) starting from O(g){O}(\mathrm{g}) is endothermic by 603 kJ mol−1603 \mathrm{~kJ} \mathrm{~mol}^{-1}. If electron affinity of O(g){O}(\mathrm{g}) is −141 kJ mol−1-141 \mathrm{~kJ} \mathrm{~mol}^{-1}, the second electron affinity of oxygen would be:
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Correct option: A
+744 kJ mol−1+744 \mathrm{~kJ} \mathrm{~mol}^{-1}
Option A (+744 kJ mol⁻¹) is correct because it represents the energy required to add a second electron to O⁻(g), calculated from the overall endothermic formation of O²⁻(g).

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