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JEE CHEMISTRY MCQ: CHEMICAL KINETICS

1 Hard
1 of 1
Analyzing +4 | -1
Correct statements in the following are

a) In Hg(t)+Cl2(g)→HgCl2(s)\mathrm{Hg}_{(t)}+\mathrm{Cl}_{2(g)} \rightarrow \mathrm{HgCl}_{2(s)}, the rate of disappearance of any of the reactants is same as the rate of appearance of the product

b) In 2HI(g)→H2(g)+I2(g)2 \mathrm{HI}_{(g)} \rightarrow \mathrm{H}_{2(g)}+\mathrm{I}_{2(g)}, the rate of consumption of HI\mathrm{HI} is half of rate of formation of H2\mathrm{H}_2 or I2\mathrm{I}_2

c) In 5Br−(aq)+BrO3−(aq)+6H+(aq)→3Br2(aq)+3H2O(I)\underset{(a q)}{5 \mathrm{Br}^{-}}+\underset{(\mathrm{aq})}{\mathrm{BrO}_3^{-}}+\underset{(\mathrm{aq})}{6 \mathrm{H}^{+}} \rightarrow \underset{(\mathrm{aq})}{3 \mathrm{Br}_2}+3 \mathrm{H}_2 \mathrm{O}(\mathrm{I}), the rate of consumption of Br−(aq)\mathrm{Br}^{-}(\mathrm{aq}) is 1.66 times to the rate of a formation of Br2\mathrm{Br}_2
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Correct option: C
a, c only correct
Option C is correct because statements a and c are correct regarding the rate of reaction.

More Questions from CHEMICAL KINETICS

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The reaction A2+B2→2AB\mathrm{A}_2+\mathrm{B}_2 \rightarrow 2 \mathrm{AB} follows the mechanism

A2⇌k−1k1A+A (fast) A+B2→k2AB+B (slow) A+B→AB (fast) \begin{aligned} & {{\text{A}}_2}\mathop \rightleftharpoons \limits_{{{\text{k}}_{ - 1}}}^{{{\text{k}}_1}} {\text{A}} + {\text{A (fast) }} \\ & \mathrm{A}+\mathrm{B}_2 \xrightarrow{\mathrm{k}_2} \mathrm{AB}+\mathrm{B} \text { (slow) } \\ & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{AB} \text { (fast) } \end{aligned}

The overall order of the reaction is:
For the first order reaction with the rate constant kk, which expression gives the rate half-life period? (Initialconc.=a)(Initial\mathrm{ }conc.\mathrm{ } = a) Which of the following is a zero order reaction? For a certain reaction involving a single reactant, it is found that C0TC_0 \sqrt{T} is constant, where C0C_0 is the initial concentration of the reactant and TT is the half-life. What is the order of the reaction? Arrhenius equation is The energy of activation for an uncatalysed reaction is 100 kJ/mol.100 \mathrm{~kJ/mol}. Presence of a catalyst lowers the energy of activation by 75%75 \%. The log⁡10K2K1\log _{10} \frac{K_2}{K_1} of the ratio of rate constant of catalysed and uncatalysed reactions at 27∘C27^{\circ} \mathrm{C} is?

Assume the frequency factor is same for both reactions. (Given 2.303×8.314=19.1472.303 \times 8.314=19.147)
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