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NEET UG CHEMISTRY MCQ: 14 TH GROUP ELEMENTS (P-BLOCK)

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Analyzing +4 | -1
[SF6]2−{\left[ {S{F_6}} \right]^{2 - }} is well known whereas [SiCl6]2−{\left[ {SiC{l_6}} \right]^{2 - }} not. The main reason is/are:
I) Six large chloride ions cannot be accommodated around Si4+S{i^{4 + }} due to limitation of its size.
II) Interaction between lone pair of Cl−C{l^ - } ion and Si4+S{i^{4 + }} ion is not very strong.
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Correct option: C
Both are correct
Option C (Both are correct) is correct because six large chloride ions cannot be accommodated around the small Si4+Si^{4+} ion, and the interaction between the lone pair of Cl−Cl^- and Si4+Si^{4+} is weak.

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