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JEE CHEMISTRY MCQ: Equilibrium

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Analyzing +4 | -1
Statement (S): The [H+]\left[\mathrm{H}^{+}\right]in 10āˆ’8Ā NHCl10^{-8} \mathrm{~N} \mathrm{HCl} is 1.05Ɨ10āˆ’7M1.05 \times 10^{-7} \mathrm{M}.

Explanation(E): The H+\mathrm{H}^{+}is obtained from HCl\mathrm{HCl} and H2O\mathrm{H}_2 \mathrm{O}; the later furnishes less H+\mathrm{H}^{+}than 10āˆ’710^{-7} due to common ion effect.
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Correct option: C
Both S and E are correct and E is correct explanation for S
The correct answer is C because both the statement and the explanation are correct, and the explanation correctly justifies why the [H+] in 10-8 N HCl is slightly higher than 10-7 M due to the contribution from water.

More Questions from Equilibrium

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The indicator used in titrating oxalic acid with caustic soda solution is: K1\mathrm{K}_1 and K2\mathrm{K}_2 are equilibrium constant for reactions (i) and (ii)

N2(Ā g)+O2(Ā g)ā‡Œ2NO(g)…\mathrm{N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})\quad\ldots (i)

NO(g)ā‡Œ12Ā N2(Ā g)+12O2(Ā g)…\mathrm{NO}(\mathrm{g}) \rightleftharpoons \frac{1}{2} \mathrm{~N}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})\quad\ldots (ii)

Then,
Ka1,   Ka2   and   Ka3K{a_1},\,\,\,K{a_2}\,\,\,\mathrm{and}\,\,\,K{a_3} are the respective ionisation constants for the following reactions
H2S⇋H++HSāˆ’HSāˆ’ā‡‹H++S2āˆ’H2S⇋2H++S2āˆ’\begin{array}{l} {H_2}S\leftrightharpoons{H^ + } + H{S^ - }\\ H{S^ - }\leftrightharpoons{H^ + } + {S^{2 - }}\\ {H_2}S\leftrightharpoons2{H^ + } + {S^{2 - }} \end{array}
The correct relationship between Ka1,  Ka2 ,Ka3K{a_1},\,\,K{a_2}\,,K{a_3} is
The pH\mathrm{pH} of 0.1Ā Māˆ’N2H40.1 \mathrm{~M}-\mathrm{N}_2 \mathrm{H}_4 solution is (For N2H4,\mathrm{N}_2 \mathrm{H}_4, Kb1=3.6Ɨ10āˆ’6,Kb2=6.4Ɨ10āˆ’12,log⁔2=0.3K_{{b}_1}=3.6 \times 10^{-6}, K_{{b}_2}=6.4 \times 10^{-12}, \log 2=0.3, log⁔3=0.48\log 3=0.48) Reaction BaO2(s)ā‡ŒBaO(s)+O2(g);Ī”H=āˆ’ve.{\text{Ba}}{{\text{O}}_2}(s) \rightleftharpoons {\text{BaO}}(s) + {{\text{O}}_2}(g);\Delta H = - {\text{ve}}. In equilibrium condition pressure of O2\text{O}_2 depends on: A : At equilibrium concentration of the reactant and product does not change with time for a chemical reaction.
R: The rate of reaction is zero at equilibrium.
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