For a first order reaction $k = 100\;{{\rm{s}}^{ - 1}}{\rm{.}}$ The time for completion of 50% reaction is

JEE CHEMISTRY MCQ: CHEMICAL KINETICS

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For a first order reaction

k = 100\;{\mathrm{s}^{ - 1}}\mathrm{.}

The time for completion of 50% reaction is

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Correct option: C

7 mili-second

Option C (7 mili-second) is correct because it is the approximate half-life calculated for a first-order reaction with the given rate constant.

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\mathrm{A}_2+\mathrm{B}_2 \rightarrow 2 \mathrm{AB}

\begin{aligned} & {{\text{A}}_2}\mathop \rightleftharpoons \limits_{{{\text{k}}_{ - 1}}}^{{{\text{k}}_1}} {\text{A}} + {\text{A (fast) }} \\ & \mathrm{A}+\mathrm{B}_2 \xrightarrow{\mathrm{k}_2} \mathrm{AB}+\mathrm{B} \text { (slow) } \\ & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{AB} \text { (fast) } \end{aligned}

k

(Initial\mathrm{ }conc.\mathrm{ } = a)

C_0 \sqrt{T}

C_0

T

100 \mathrm{~kJ/mol}.

75 \%

\log _{10} \frac{K_2}{K_1}

27^{\circ} \mathrm{C}

2.303 \times 8.314=19.147