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JEE CHEMISTRY MCQ: Equilibrium

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Analyzing +4 | -1
The concentration of KIā€…ā€Šandā€…ā€ŠKCl\mathrm{KI }\;\mathrm{and}\;\mathrm{ KCl} in a certain solution containing both is 0.001 M each. If 20 mL of this solution is added to 20 mL of a saturated solution of AgI in water. What will happen?

(Kspā€…ā€ŠAgCl=10āˆ’10,ā€…ā€ŠKspā€…ā€ŠAgI=10āˆ’16)({K_{\mathrm{sp}}}\;\mathrm{AgCl} = {10^{ - 10}},\;{K_{\mathrm{sp}}}\;\mathrm{AgI} = {10^{ - 16}})
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Correct option: A
AgI\mathrm{AgI} will be precipitated
Option A (AgI will be precipitated) is correct because the addition of KI increases the iodide ion concentration, causing the ionic product of AgI to exceed its solubility product, leading to precipitation.

More Questions from Equilibrium

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The indicator used in titrating oxalic acid with caustic soda solution is: K1\mathrm{K}_1 and K2\mathrm{K}_2 are equilibrium constant for reactions (i) and (ii)

N2(Ā g)+O2(Ā g)ā‡Œ2NO(g)…\mathrm{N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})\quad\ldots (i)

NO(g)ā‡Œ12Ā N2(Ā g)+12O2(Ā g)…\mathrm{NO}(\mathrm{g}) \rightleftharpoons \frac{1}{2} \mathrm{~N}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})\quad\ldots (ii)

Then,
Ka1,   Ka2   and   Ka3K{a_1},\,\,\,K{a_2}\,\,\,\mathrm{and}\,\,\,K{a_3} are the respective ionisation constants for the following reactions
H2S⇋H++HSāˆ’HSāˆ’ā‡‹H++S2āˆ’H2S⇋2H++S2āˆ’\begin{array}{l} {H_2}S\leftrightharpoons{H^ + } + H{S^ - }\\ H{S^ - }\leftrightharpoons{H^ + } + {S^{2 - }}\\ {H_2}S\leftrightharpoons2{H^ + } + {S^{2 - }} \end{array}
The correct relationship between Ka1,  Ka2 ,Ka3K{a_1},\,\,K{a_2}\,,K{a_3} is
The pH\mathrm{pH} of 0.1Ā Māˆ’N2H40.1 \mathrm{~M}-\mathrm{N}_2 \mathrm{H}_4 solution is (For N2H4,\mathrm{N}_2 \mathrm{H}_4, Kb1=3.6Ɨ10āˆ’6,Kb2=6.4Ɨ10āˆ’12,log⁔2=0.3K_{{b}_1}=3.6 \times 10^{-6}, K_{{b}_2}=6.4 \times 10^{-12}, \log 2=0.3, log⁔3=0.48\log 3=0.48) Reaction BaO2(s)ā‡ŒBaO(s)+O2(g);Ī”H=āˆ’ve.{\text{Ba}}{{\text{O}}_2}(s) \rightleftharpoons {\text{BaO}}(s) + {{\text{O}}_2}(g);\Delta H = - {\text{ve}}. In equilibrium condition pressure of O2\text{O}_2 depends on: A : At equilibrium concentration of the reactant and product does not change with time for a chemical reaction.
R: The rate of reaction is zero at equilibrium.
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