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NEET UG CHEMISTRY MCQ: CHEMICAL BONDING & MOLECULAR STRUCTURE

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Application +4 | -1
The hybridization and magnetic behaviour of cobalt ion in [Co(NH3)6]3+\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+} complex, respectively is
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Correct option: D
d2sp3\mathrm{d}^{2} \mathrm{sp}^{3} and diamagnetic
Option D (d2sp3\mathrm{d}^{2} \mathrm{sp}^{3} and diamagnetic) is correct because in the complex [Co(NH3)6]3+[Co(NH_3)_6]^{3+}, cobalt is in +3 oxidation state, leading to a d6d^6 configuration. NH3NH_3 is a strong field ligand, causing pairing of electrons and resulting in d2sp3d^2sp^3 hybridization and a diamagnetic nature.

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