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JEE CHEMISTRY MCQ: HALOALKANES AND HALO ARENES
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Understanding
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Predict the order of reactivity of the following four isomers towards reaction.
(I)
(II)
(III)
(IV)
(I)
(II)
(III)
(IV)
View answer and explanation
Correct option: C
(I) (III) (II) (IV)
Option D (I > II > III > IV) is correct because the reactivity of reactions decreases with increasing steric hindrance. Primary halides are more reactive than secondary, which are more reactive than tertiary.
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.
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Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass. Friedel-Craft’s reaction of bromobenzene with methyl iodide gives:
