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JEE CHEMISTRY MCQ: HALOALKANES AND HALO ARENES

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Analyzing +4 | -1
The major product of the following reaction is:
CH3−CHCl∣−CH3→(ii) HBr, peroxide(iii)aq.KOH (i) Alc. KOHC{H_3} - \mathop {CH}\limits^{\begin{array}{cccccccccccccccccccc} {Cl} \\ | \end{array}} - C{H_3}\xrightarrow[{\begin{array}{cccccccccccccccccccc} {(ii){\text{ }}HBr,{\text{ peroxide}}} \\ {\left( {iii} \right){\kern 1pt} {\kern 1pt} {\text{aq}}.{\kern 1pt} {\kern 1pt} KOH} \end{array}}]{{{\text{ }}(i){\text{ Alc}}.{\text{ }}KOH}}
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Correct option: B
CH3−CH2−CH2−OHC{H_3} - C{H_2} - C{H_2} - OH
The correct answer is B (CH3−CH2−CH2−OHC{H_3} - C{H_2} - C{H_2} - OH) because the reaction sequence involves anti-Markovnikov addition of HBr followed by substitution with KOH.

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