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JEE CHEMISTRY MCQ: ALDEHYDES & KETONES & CARBOXYLIC ACIDS
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Why the aromatic carboxylic acids do not undergo Friedel-Crafts reaction?
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Correct option: B
Carboxyl group act as a deactivating and ortho-directing group
Option D is correct because the carboxyl group deactivates the benzene ring and the catalyst (AlCl3) coordinates with the carboxyl group, preventing it from acting as a Lewis acid.
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By passing water gas through an electric discharge at low pressure, we get:
Addition of alcohols to aldehydes and ketones takes place in presence of dry gas because it
(i) Protonates the oxygen of the carbonyl compounds
(ii) Increases the electrophilicity of the carbonyl carbon
(iii) Removes the excess moisture from the reaction
(iv) Helps the reaction to move in the forward direction Benzyl alcohol and sodium benzoate is obtained by the action of sodium hydroxide on benzaldehyde. This reaction is known as Which one of the following reactions is a condensation reaction? Carboxylic acids dimerise due to The number of aldehyde isomers for will be
(i) Protonates the oxygen of the carbonyl compounds
(ii) Increases the electrophilicity of the carbonyl carbon
(iii) Removes the excess moisture from the reaction
(iv) Helps the reaction to move in the forward direction Benzyl alcohol and sodium benzoate is obtained by the action of sodium hydroxide on benzaldehyde. This reaction is known as Which one of the following reactions is a condensation reaction? Carboxylic acids dimerise due to The number of aldehyde isomers for will be