JEE CHEMISTRY MCQ: THERMODYNAMICS

1 Medium

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Analyzing +4 | -1

Statement I : In the following reaction,

CO(g) + 1/2O(g) \to C{O_2}(g);\Delta H = - 68\,\,k\,cal

and thus,

{\Delta _f}H(C{O_2}) = - 68\,\,k\,cal\,\,mo{l^{ - 1}}

Statement II : 1 mol of

C{O_2}

is formed and enthalpy change is the heat of formation of

C{O_2}

View answer and explanation

Correct option: D

Both statements are incorrect

Both statements are incorrect because the standard enthalpy of formation requires elements to be in their standard states, and the given reaction does not involve elements in their standard states.

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Consider following reactions
I:

\ \mathrm{C}(\mathrm{s})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})-\mathrm{CO}(\mathrm{g}), \Delta \mathrm{H}_1=\mathrm{a}

II:

\mathrm{CO}(\mathrm{g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})-\mathrm{CO}_2(\mathrm{~g}), \Delta \mathrm{H}_2=\mathrm{b}

III:

\mathrm{C}(\mathrm{s})+\mathrm{CO}_2(\mathrm{~g})-2 \mathrm{CO}(\mathrm{g}) ; \Delta \mathrm{H}_3=\mathrm{c}

Select the correct statement When

0.18 \mathrm{~g}

of glucose was burnt in a bomb calorimeter, the temperature rose by

4 \mathrm{~K}.

The heat capacity of the calorimeter system is

\left(\Delta_{\mathrm{C}} \text{H}^{\circ}=-2.8\times 10^6 \mathrm{~J} / \mathrm{mol} \text{ glucose}\right)

Statement-1:

{CsI}

is less soluble in water compared to

{CsCl}

Satement-2: More amount of heat is liberated during the formation of

{CsCl}

than the formation

{Cs} I

from their elements Consider the following processes :

\begin{array}{cccccccccccccccccccc} {}&{\Delta H(KJ/mol)} \\ {1/2A \to B}&{ + 150} \\ {3B \to 2C + D}&{ - 125} \\ {E + A \to 2D}&{ + 350} \end{array}

For

{B}+{D} \rightarrow {E}+2 {C}, \Delta {H}

will be : The difference b/w

\Delta H

and

\Delta u

at constant volume is equal to The heat evolved in the combustion of methane is given by the following equations

\mathrm{C}{\mathrm{H}_4}\left( \mathrm{g} \right) + 2{\mathrm{O}_2}\left( \mathrm{g} \right) \to \mathrm{C}{\mathrm{O}_2}\left( \mathrm{g} \right) + {\mathrm{H}_2}\mathrm{O}\left( l \right);\Delta H = - 890.3\mathrm{kJ}

How many grams of methane would be required to produce 44.15 kJ of heat of combustion?