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NEET UG CHEMISTRY MCQ: HALOALKANES AND HALO ARENES

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CH3−CH−CH2−CH3→UVCl2A (major), AC{H_3} - CH - C{H_2} - C{H_3}\xrightarrow[{UV}]{{C{l_2}}}A\,\left( {\mathrm{major}} \right),\,A is
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Correct option: B
CH3−C∣Cl∣CH3−CH2−CH3C{H_3} - \mathop {\mathop C\limits_{\mathop |\limits_{Cl} } }\limits^{\mathop |\limits^{C{H_3}} } - C{H_2} - C{H_3}
Option B (CH3−C∣Cl∣CH3−CH2−CH3C{H_3} - \mathop {\mathop C\limits_{\mathop |\limits_{Cl} } }\limits^{\mathop |\limits^{C{H_3}} } - C{H_2} - C{H_3}) is correct because chlorination of alkanes under UV light follows a free radical mechanism, and the most stable radical is formed at the most substituted carbon.

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