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JEE CHEMISTRY MCQ: ALCOHOLS & PHENOLS & ETHERS

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Replacement of Cl\mathrm{Cl} of chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-dinitrochlorobenzene is readily replaced because:
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Correct option: D
NO2\mathrm{N}{\mathrm{O}_2} withdraws electrons at orthoortho and parapara positions
Option D is correct because the nitro groups (-NO2) are electron-withdrawing groups that stabilize the negative charge formed during the nucleophilic aromatic substitution at the ortho and para positions, making the chlorine more easily replaced.

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