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NEET UG CHEMISTRY MCQ: AMINES

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An organic compound ‘A’ having molecular formula C2H3N{\mathrm{C}_2}{\mathrm{H}_3}\mathrm{N} on reduction gave another compound B, upon treatment with nitrous acid ‘B’ gave ethyl alcohol. On warming with chloroform and alcoholic KOH\mathrm{KOH}, it formed an offensive smelling compound ‘C’. The compound ‘C’ is
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Correct option: B
CH3CH2N=→C\mathrm{C}{\mathrm{H}_3}\mathrm{C}{\mathrm{H}_2}\mathrm{N}\mathop = \limits^ \to \mathrm{C}
Option B (CH3CH2N=→C\mathrm{C}{\mathrm{H}_3}\mathrm{C}{\mathrm{H}_2}\mathrm{N}\mathop = \limits^ \to \mathrm{C}) is correct because the reaction sequence describes the carbylamine reaction, which produces an isocyanide.

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