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JEE CHEMISTRY MCQ: ALCOHOLS & PHENOLS & ETHERS

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ROH+PCl3→RCl+A\mathrm{ROH}+\mathrm{PCl}_3 \rightarrow \mathrm{RCl}+\mathrm{A}

ROH+PCl5→RCl+B\mathrm{ROH}+\mathrm{PCl}_5 \rightarrow \mathrm{RCl}+\mathrm{B}

Compounds B and A are respectively:
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Correct option: D
POCl3,H3PO3\mathrm{POCl}_3, \mathrm{H}_3 \mathrm{PO}_3
Option D (POCl3,H3PO3\mathrm{POCl}_3, \mathrm{H}_3 \mathrm{PO}_3) is correct because the reaction of ROH with PCl5 yields POCl3 and the reaction with PCl3 yields H3PO3.

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