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NEET UG CHEMISTRY MCQ: STATES OF MATTER

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Analyzing +4 | -1
Which of the following statements on critical constants of gases are correct?

I. Larger the Tc/pcT_c / p_c value of a gas, larger would be the excluded volume.

II. Critial temperature (Tc)\left(T_c\right) of a gas is greater than its Boyle temperature (TB)\left(T_B\right).
III. At the critial point in the van der Waals' gas isotherm.

(∂p∂Vm)Tc=0\left(\frac{\partial p}{\partial V_m}\right)_{T_c}=0

Select the correct answer using the codes given below.
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Correct option: B
Both I and III
Option B (Both I and III) is correct because statement I correctly relates Tc/Pc to excluded volume, and statement III correctly describes the condition at the critical point.

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