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NEET UG CHEMISTRY MCQ: SOLID STATE

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Analyzing +4 | -1
If the positions of Na+\mathrm{N}{\mathrm{a}^ + } and Cl−\mathrm{C}{\mathrm{l}^ - } are interchanges in NaCl, the crystal lattice with respect to Na+\mathrm{N}{\mathrm{a}^ + } and Cl−\mathrm{C}{\mathrm{l}^ - } is :
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Correct option: C
Fcc and bcc
Option C (Fcc and bcc) is correct because in NaCl, Na+ ions occupy octahedral voids in the fcc lattice of Cl- ions. Interchanging their positions results in Cl- ions occupying octahedral voids in the fcc lattice of Na+ ions, effectively creating a bcc arrangement for Cl- with respect to Na+.

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