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NEET UG CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Phosphate + conc. HNO3+(NH4)2  MoO4HN{O_3} + {\left( {N{H_4}} \right)_2}\;Mo{O_4} solution →\to Yellow precipitate.
The composition of yellow precipitate is:
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Correct option: B
(NH4)3PO4.12MoO3{\left( {N{H_4}} \right)_3}P{O_4}.12Mo{O_3}
Option B ((NH4)3PO4.12MoO3{\left( {N{H_4}} \right)_3}P{O_4}.12Mo{O_3}) is correct because the yellow precipitate formed in the reaction of phosphate with concentrated nitric acid and ammonium molybdate is ammonium phosphomolybdate, which has the formula (NH4)3[P(Mo12O40)](NH_4)_3[P(Mo_{12}O_{40})].

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