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JEE CHEMISTRY MCQ: CHEMICAL KINETICS

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Analyzing +4 | -1
For the reaction 2NH3→N2+3H22 \mathrm{NH}_3 \rightarrow \mathrm{N}_2+3 \mathrm{H}_2,

−d[NH3]dt=k1[NH3],−d[N2]dt=k2[NH3],d[H2]dt=k3[NH3]-\frac{\mathrm{d}\left[\mathrm{NH}_3\right]}{\mathrm{d} t}=k_1\left[\mathrm{NH}_3\right],-\frac{\mathrm{d}\left[\mathrm{N}_2\right]}{\mathrm{d} t}=k_2\left[\mathrm{NH}_3\right], \frac{\mathrm{d}\left[\mathrm{H}_2\right]}{\mathrm{d} t}=k_3\left[\mathrm{NH}_3\right]

Then relation between k1,k2k_1, k_2 and k3k_3 is
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Correct option: A
1.5k1=3k2=k31.5 k_1=3 k_2=k_3
Option A (1.5k1=3k2=k31.5 k_1=3 k_2=k_3) is correct because it correctly relates the rate constants based on the stoichiometry of the reaction.

More Questions from CHEMICAL KINETICS

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The reaction A2+B2→2AB\mathrm{A}_2+\mathrm{B}_2 \rightarrow 2 \mathrm{AB} follows the mechanism

A2⇌k−1k1A+A (fast) A+B2→k2AB+B (slow) A+B→AB (fast) \begin{aligned} & {{\text{A}}_2}\mathop \rightleftharpoons \limits_{{{\text{k}}_{ - 1}}}^{{{\text{k}}_1}} {\text{A}} + {\text{A (fast) }} \\ & \mathrm{A}+\mathrm{B}_2 \xrightarrow{\mathrm{k}_2} \mathrm{AB}+\mathrm{B} \text { (slow) } \\ & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{AB} \text { (fast) } \end{aligned}

The overall order of the reaction is:
For the first order reaction with the rate constant kk, which expression gives the rate half-life period? (Initialconc.=a)(Initial\mathrm{ }conc.\mathrm{ } = a) Which of the following is a zero order reaction? For a certain reaction involving a single reactant, it is found that C0TC_0 \sqrt{T} is constant, where C0C_0 is the initial concentration of the reactant and TT is the half-life. What is the order of the reaction? Arrhenius equation is The energy of activation for an uncatalysed reaction is 100 kJ/mol.100 \mathrm{~kJ/mol}. Presence of a catalyst lowers the energy of activation by 75%75 \%. The log⁡10K2K1\log _{10} \frac{K_2}{K_1} of the ratio of rate constant of catalysed and uncatalysed reactions at 27∘C27^{\circ} \mathrm{C} is?

Assume the frequency factor is same for both reactions. (Given 2.303×8.314=19.1472.303 \times 8.314=19.147)
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