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JEE CHEMISTRY MCQ: ALCOHOLS & PHENOLS & ETHERS

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Given below are two statements.

Statement-I: Phenol reacts with bromine in CCl4{CCl}_4 gives a white ppt. of 2,4,6-tribromophenol.

Statement-II : Phenol reacts with dil. HNO3{HNO}_3 at 0−10∘C0-10^{\circ} \mathrm{C} to form o- and p-nitrophenol

Choose the most appropriate answer from given below options:
View answer and explanation
Correct option: D
Statement-I is incorrect and Statement-II is correct
The correct answer is D (Statement-I is incorrect and Statement-II is correct) because phenol reacts with bromine water to give a white precipitate of 2,4,6-tribromophenol, but with bromine in CCl4, it gives a mixture of ortho and para bromophenols. Phenol reacts with dilute HNO3 at 0-10°C to form o- and p-nitrophenol is correct.

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