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JEE CHEMISTRY MCQ: SOLUTIONS

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Analyzing +4 | -1
Consider the following statements.

I. The PH{P}_{{H}} of a mixture containing 400 ml400\, {ml} of 0.1M H2SO40.1 {M} \,{H}_2 {SO}_4 and 400 ml400 \,{ml} of 0.1 M NaOH0.1 \,{M}\, {NaOH} will be approximately 1.3

II. Ionic product of water is temperature dependent

III. Le-chatelier's principle is applicable to common-ion effect

IV. A mixture of HClO4+NaClO4{HClO}_4+{NaClO}_4 acts as an acidic buffer.

The correct statements are
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Correct option: D
I, II and III
Option D (I, II and III) is correct because the pH calculation, the temperature dependence of the ionic product of water, and the applicability of Le Chatelier's principle to the common-ion effect are all valid statements.

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An aqueous solution of a solute which neither associates nor dissociates has a freezing point depression of X∘C.\mathrm{X}^{\circ} \mathrm{C}. An equimolal solution of a second salt has a freezing point depression of 3X∘C.3 \mathrm{X}^{\circ} \mathrm{C}. Assuming 100%100 \% dissociation of salt, the second solution could be a salt of formula Read the following statements carefully and choose the correct option

(i) Osmotic pressure is not a colligative property.

(ii) For dilute solutions, osmotic pressure is proportional to the molarity, C{C} of the solution at a given temperature TT.

(iii) During osmosis, solvent molecules always flow from higher concentration to lower concentration of solution.

(iv) The osmotic pressure has been found to depend on the concentration of the solution
A solution that obeys Raoult’s law is called When two liquids AA and BB are mixed they form an ideal solution. At certain temperature the V.P. of the solution, that contains 3 moles of AA and 1 mole of BB was found to be 550 mm550 \mathrm{~mm} of Hg\mathrm{Hg}. The vapour pressure of a solution containing 4 moles of AA and 1 mole of BB was found to be 560 mm\mathrm{mm} of Hg\mathrm{Hg}. The vapour pressure of pure liquid AA is Equal masses of two aqueous solutions, one of 3.6 g3.6 \, \mathrm{g} glucose per 100 g100 \mathrm{~g} of water and the other of 3.6 g3.6 \mathrm{~g} urea per 100 g100 \mathrm{~g} of water are mixed. If the freezing point of resulting solution is −x∘C,-x^{\circ} \mathrm{C}, then the value of '1000x1000 x' is (Kf\left(K_{\mathrm{f}}\right. of water =1.86)\left.=1.86\right) Information

I. Semipermeable membrane contains network of submacroscopic holes or pores.

II. Semipermeable membrane appears to be continuous sheets or films.

III. Solvent molecules cannot pass through the holes of semipermeable membrane but solute molecules can pass On the basis of the information given above select the correct option.
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