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JEE CHEMISTRY MCQ: Equilibrium

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Understanding +4 | -1
The hydrolysis constant for ZnCl2\mathrm{ZnCl}_2 will be

Where, Kb{K}_{\mathrm{b}} is effective dissociation constant of base Zn++\mathrm{Zn}^{++}
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Correct option: B
Kh=Kw2KbK_h=\frac{K_w^2}{K_b}
Option A (Kh=Kw/Kb) is correct because the hydrolysis constant for a salt of a weak base and strong acid is given by Kw/Kb.

More Questions from Equilibrium

Practice All Chapter MCQs β†’
The indicator used in titrating oxalic acid with caustic soda solution is: K1\mathrm{K}_1 and K2\mathrm{K}_2 are equilibrium constant for reactions (i) and (ii)

N2(Β g)+O2(Β g)β‡Œ2NO(g)…\mathrm{N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})\quad\ldots (i)

NO(g)β‡Œ12Β N2(Β g)+12O2(Β g)…\mathrm{NO}(\mathrm{g}) \rightleftharpoons \frac{1}{2} \mathrm{~N}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})\quad\ldots (ii)

Then,
Ka1,   Ka2   and   Ka3K{a_1},\,\,\,K{a_2}\,\,\,\mathrm{and}\,\,\,K{a_3} are the respective ionisation constants for the following reactions
H2S⇋H++HSβˆ’HSβˆ’β‡‹H++S2βˆ’H2S⇋2H++S2βˆ’\begin{array}{l} {H_2}S\leftrightharpoons{H^ + } + H{S^ - }\\ H{S^ - }\leftrightharpoons{H^ + } + {S^{2 - }}\\ {H_2}S\leftrightharpoons2{H^ + } + {S^{2 - }} \end{array}
The correct relationship between Ka1,  Ka2 ,Ka3K{a_1},\,\,K{a_2}\,,K{a_3} is
The pH\mathrm{pH} of 0.1Β Mβˆ’N2H40.1 \mathrm{~M}-\mathrm{N}_2 \mathrm{H}_4 solution is (For N2H4,\mathrm{N}_2 \mathrm{H}_4, Kb1=3.6Γ—10βˆ’6,Kb2=6.4Γ—10βˆ’12,log⁑2=0.3K_{{b}_1}=3.6 \times 10^{-6}, K_{{b}_2}=6.4 \times 10^{-12}, \log 2=0.3, log⁑3=0.48\log 3=0.48) Reaction BaO2(s)β‡ŒBaO(s)+O2(g);Ξ”H=βˆ’ve.{\text{Ba}}{{\text{O}}_2}(s) \rightleftharpoons {\text{BaO}}(s) + {{\text{O}}_2}(g);\Delta H = - {\text{ve}}. In equilibrium condition pressure of O2\text{O}_2 depends on: A : At equilibrium concentration of the reactant and product does not change with time for a chemical reaction.
R: The rate of reaction is zero at equilibrium.
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