JEE CHEMISTRY MCQ: REDOX REACTIONS

1 Medium

1 of 1

Analyzing +4 | -1

Statement-I: Equivalent weight of

\mathrm{KMnO}_4

in acidic medium is

\mathrm{M} / 5

(

\mathrm{M}=

molecular weight) while in strongly basic medium, it is equal to

\text{M/3}.

Statement-II: In acidic medium, 1 mol of

\mathrm{MnO}_4^{-}

gains 5 mole electrons while in strongly basic medium it gains 3 mole electrons.

View answer and explanation

Correct option: B

Both the statements are incorrect

Option D (Statement-I is incorrect but statement-II is correct) is correct because the equivalent weight of KMnO4 in acidic medium is M/5, but in strongly basic medium, it is M/1, and the electron gain is correctly stated.

More Questions from REDOX REACTIONS

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The oxidation number of

\mathrm{H}

in sodium hydride is A reagent, which can decrease the oxidation number of an element, is called Consider the following decomposition reaction

2 \mathrm{KClO}_3 \longrightarrow 2 \mathrm{KCl}+3 \mathrm{O}_2

In the above reaction, Assertion (A):

\mathrm{HNO}_3

acts as oxidizing agent.

Reason (R): Oxidation no. of nitrogen is +5, no increase in oxidation no. beyond +5 can occur. The oxidation no. of

\mathrm{HNO}_3

can only decrease. Assertion :- Bromide ion is serving as a reducing agent in the reaction.

\mathrm{MnO}_4^{-}(\mathrm{aq})+\mathrm{Br}^{-}(\mathrm{aq})+\mathrm{H}_2 \mathrm{O} \longrightarrow 2 \mathrm{MnO}_2(\mathrm{aq})+\mathrm{BrO}_3^{-}(\mathrm{aq})+2 \mathrm{OH}^{-}(\mathrm{aq})

Reason :- Oxidation number of

\mathrm{Br}

increases from

-1

+5.

A substance, that by its sharp colour change indicates the completion of reaction is known as :