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JEE CHEMISTRY MCQ: d & f- BLOCK ELEMENTS

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Analyzing +4 | -1
I2+Na2CO3{I}_2+{Na}_2 {CO}_3 soln.⟶ΔX+Y^{\mathrm{n}} . \stackrel{\Delta}{\longrightarrow} {X}+{Y}

If 'X{X}' gives coloured ppt. with Pb(CH3COO)2{Pb}\left({CH}_3 {COO}\right)_2 solution, then 'Y{Y}' will not be respond to which of the following
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Correct option: B
Y+Cr2O72−(aq)+OH−(aq){Y}+{Cr}_2 {O}_7{ }^{2-}\text{(aq)} +{OH}^{-}(\mathrm{aq})
The reaction produces NaI (X) and NaIO3 (Y). NaI gives a colored precipitate with lead acetate. NaIO3 is an oxidizing agent and will not oxidize Cr2O72- in a basic medium. Therefore, the correct answer is B.

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