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JEE CHEMISTRY MCQ: SOME BASIC CONCEPTS OF CHEMISTRY

1 Medium
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Application +4 | -1
Hydrazine reacts with KIO3\mathrm{KIO}_3 in presence of HCl\mathrm{HCl} as

N2H4+IO3−+2H++Cl−⟶ICl+N2+3H2O\mathrm{N}_2 \mathrm{H}_4+\mathrm{IO}_3^{-}+2 \mathrm{H}^{+}+\mathrm{Cl}^{-} \longrightarrow \mathrm{ICl}+\mathrm{N}_2+3 \mathrm{H}_2 \mathrm{O}

The equivalent masses of N2H4\mathrm{N}_2 \mathrm{H}_4 and KIO3\mathrm{KIO}_3 respectively are:
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Correct option: A
8 and 53.5
Option A (8 and 53.5) is correct because the equivalent mass of N2H4N_2H_4 is calculated based on the change in oxidation number of nitrogen, and the equivalent mass of KIO3KIO_3 is calculated based on the change in oxidation number of iodine.

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