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JEE CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Analyzing +4 | -1

During electrolysis of sulphuric acid, which of the following processes is possible at anode?

A.

2 {H}_2 {O}({l}) \longrightarrow {O}_2({~g})+4 {H}^{+}({aq})+4 {e}^{-} \stackrel{\ominus}{{E}_{\text {cell }}}=+1.23 {~V}

B.

2 {SO}_4^{2-}({aq}) \longrightarrow {S}_2 {O}_8^{2-}({aq})+2 {e}^{-} \stackrel{\ominus}{{E}_{\text {cell }}}= 1.96 {~V}

Choose the correct option based on following statements.

(i) Process A is preferred at higher concentration of sulphuric acid.

(ii) Process B is preferred at higher concentration of sulphuric acid.

(iii) Process A is preferred for dilute sulphuric acid.

(iv) Process B is preferred for dilute sulphuric acid.

(v) Both A and B are equally possible at higher concentration.

View answer and explanation

Correct option: B

(iii) and (ii)

Option B ((iii) and (ii)) is correct because process A is favored in dilute sulfuric acid, while process B is favored in concentrated sulfuric acid.

More Questions from ELECTRO CHEMISTRY

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25^{\circ} \mathrm{C}

, the standard emf of cell having reactions involving two electron change is found to be

0.295 \mathrm{~V}

. The equilibrium constant of the reaction is Which are used as secondary reference electrodes? For the following cell with hydrogen electrodes at two different pressures

{p_1}{\kern 1pt} {\kern 1pt} \mathrm{and}{\kern 1pt} {\kern 1pt} {p_2}

\mathop {\mathrm{Pt}\left( {{\mathrm{H}_2}} \right)}\limits_{{p_1}} \left| {\mathop {{\mathrm{H}^ + }\left( {aq} \right)}\limits_{1\mathrm{ }M} } \right|\mathop {Pt\left( {{\mathrm{H}_2}} \right)}\limits_{{p_2}}

emf is given by A current of strength 2.5 A was passed through

\mathrm{CuS}{\mathrm{O}_4}

solution for 6 min 26 s. The amount of copper deposited is (At. Wt. of Cu = 63.5, 1F = 96500 C) A current strength of 9.65 amperes is passed through excess fused

{AlCl}_3

for 5 hours. How many litres of chlorine will be liberated at

STP

({F}=96500 {C})

The electrode potential (in millivolts) of

2 \mathrm{Ag}(\mathrm{s})+\mathrm{S}^{2-}(\mathrm{aq}) \rightarrow \mathrm{Ag}_2 \mathrm{S}(\mathrm{s})+2 \mathrm{e}^{-}

in a solution buffered at

\mathrm{pH}=3

and which is also saturated with

0.1 \mathrm{~M}-\mathrm{H}_2 \mathrm{S},

\mathrm{H}_2 \mathrm{S}, K_{\mathrm{a}_1}=10^{-8} ; K_{\mathrm{a}_2}=10^{-13}, K_{\mathrm{sp}}

\mathrm{Ag}_2 \mathrm{S}=4 \times 10^{-48},

E^{\circ}_{{\mathrm{Ag} | \mathrm{Ag}}^{+}}=0.80 \mathrm{~V},

\log 2=0.3,

2.303 R T / F=0.06