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JEE CHEMISTRY MCQ: d & f- BLOCK ELEMENTS

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Application +4 | -1
The reaction below can be used as a laboratory method for preparing small quantities of Cl2( g)\mathrm{Cl}_2(\mathrm{~g}). If a 49 g49 \mathrm{~g} sample that is 96% K2Cr2O796 \% \mathrm{~K}_2 \mathrm{Cr}_2 \mathrm{O}_7 by mass is allowed to react with 325 mL325 \mathrm{~mL} of HCl(aq)\mathrm{HCl}_{(\mathrm{aq})} with a density of 1.15 g/ml1.15 \mathrm{~g} / \mathrm{ml} and 30.1%HCl30.1 \% \mathrm{HCl} by mass, how many grams of Cl2( g)\mathrm{Cl}_2(\mathrm{~g}) are produced?

K2Cr2O7+HCl→CrCl3+Cl2+H2O+KCl\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+\mathrm{HCl} \rightarrow \mathrm{CrCl}_3+\mathrm{Cl}_2+\mathrm{H}_2 \mathrm{O}+\mathrm{KCl}

(Atomic weights: K=39,Cr=52,Cl=35.5\mathrm{K}=39, \mathrm{Cr}=52, \mathrm{Cl}=35.5 )
View answer and explanation
Correct option: C
34.08 g34.08 \mathrm{~g}
Option C (34.08 g) is correct because it is calculated by determining the limiting reagent and then using stoichiometry to find the mass of chlorine produced.

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