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JEE CHEMISTRY MCQ: ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES

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Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?
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Correct option: B
To remove NaCN\mathrm{NaCN} and Na2 S\mathrm{Na}_2 \mathrm{~S}
Option B is correct because nitric acid is added to the sodium extract to decompose any cyanide or sulfide ions present, which would otherwise interfere with the silver nitrate test for halogens by forming precipitates.

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