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JEE CHEMISTRY MCQ: CHEMICAL BONDING & MOLECULAR STRUCTURE

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Analyzing +4 | -1
Assertion (A): In PF3Cl2,{PF}_3 {Cl}_2, fluorine occupy axial position and chlorine occupy equatorial position.

Reason (R): FF is smaller in size than Cl.Cl.
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Correct option: A
Both (A) & (R) are true and the (R) is the correct explanation of the (A)
Option A (Both (A) & (R) are true and the (R) is the correct explanation of the (A)) is correct because fluorine is smaller and more electronegative than chlorine, thus minimizing bond pair-bond pair repulsions in the axial position.

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