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NEET UG CHEMISTRY MCQ: PRACTICAL CHEMISTRY

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Analyzing +4 | -1
A NaOH\mathrm{NaOH} solution is to be standardized by titrating it against a known mass of potassium hydrogen phthalate. Which procedure will give a molarity of NaOH\mathrm{NaOH} that is too low?
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Correct option: C
Neglecting to fill the tip of the buret with
NaOH\text{NaOH} solution before titrating
Option C (Neglecting to fill the tip of the buret with NaOH\text{NaOH} solution before titrating) is correct because it results in a smaller volume of NaOH being used than recorded.

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A pale green crystalline inorganic salt (A) dissolves freely in water. It gives a brown precipitate on addition of aqueous NaOH.\mathrm{NaOH}. The solution of (A) also gives a black precipitate on bubbling H2S\mathrm{H}_2 \mathrm{S} in alkaline medium. An aqueous solution of the (A) decolorizes the pink colour of the permanganate solution. The metal in the salt solution is 100 ml100 \mathrm{~ml} of NaHC2O4\mathrm{NaHC}_2 \mathrm{O}_4 required 50 ml50 \mathrm{~ml} of 0.1 M KMnO40.1 \mathrm{~M} \, \mathrm{KMnO}_4 solution in acidic medium. Volume of 0.1 M NaOH0.1 \mathrm{~M} \mathrm{~NaOH} required by 100 ml100 \mathrm{~ml} of NaHC2O4\mathrm{NaHC}_2 \mathrm{O}_4 is The ion that cannot be precipitated by both HCl{HCl} and H2S{H}_2 {S} is The rapid change of pH near the stoichiometric point of an acid-base titration in the basis of indicator detection. pH of the solution is related to ratio of the concentrations of the conjugated acid (HIn)(HIn) and the base (In)(In) forms of the indicator by the expression. On heating colourless solid A,A, gas BB (liquid at room temp.) and gas CC are formed. AA is decomposed by NaOH\mathrm{NaOH} on heating to form gas DD giving white fumes with HCl.\mathrm{HCl}. Gas C{C} occupies 800 ml/g800 \mathrm{~ml} / \mathrm{g} at N.T.P. Hence AA is Standard HClHCl solution is titrated to a pink phenolphthalein endpoint by adding a NaOH\mathrm{NaOH} solution while stirring. If a solution becomes pink throughout but loses its color upon standing for a short time, what should be done to restore the color?
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