JEE CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

1 Hard

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Analyzing +4 | -1

The correct order for the wavelengths of absorption in the visible region for the following is

I.

\left[\mathrm{Ni}\left(\mathrm{NO}_2\right)_6\right]^{4-}

II.

\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}

III.

\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}

View answer and explanation

Correct option: C

III

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Option C (III > II > I) is correct because the wavelengths of absorption are inversely proportional to the crystal field splitting energy (CFSE), which depends on the ligand field strength (H2O < NH3 < NO2-).

More Questions from CO-ORDINATION COMPOUNDS

Practice All Chapter MCQs →

Which has maximum paramagnetic character? Ionization of

\mathrm{K}\left[ {\mathrm{Ag}{{\left( {\mathrm{CN}} \right)}_2}} \right]

will give: The cation that does not form an ammine complex with excess of ammonia is: The complexes

\left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;}

are example for isomerism The correct name of

\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\left[\mathrm{PtCl}_4\right]

is: Which of the following pairs of isomers and types of isomerism are correctly matched?

(I)

\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2

and

\left[{Co}\left({NH}_3\right)_5({ONO})\right] {Cl}_2 \ldots \ldots \ldots

Linkage

(II)

\left[{Cu}\left({NH}_3\right)_4\right]\left[{PtCl}_4\right] \,\, \& \,\, \left[{Pt}\left({NH}_3\right)_4\right]\left[{CuCl}_4\right] \ldots \ldots \ldots

Coordinations

(III)

\left[{Pt}\left({NH}_3\right)_4 {Cl}_2\right] {Br}_2 \, \, \& \, \, \left[{Pt}\left({NH}_3\right)_4 {Br}_2\right]{Cl}_2 \ldots \ldots \ldots

Ionization

Select the correct answer using the codes given below: