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JEE CHEMISTRY MCQ: ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES

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Analyzing +4 | -1
The correct decreasing order of acidity is represented by

(a) CH3−NO2\mathrm{CH}_3-\mathrm{NO}_2

(b) NO2−CH2−NO2\mathrm{NO}_2-\mathrm{CH}_2-\mathrm{NO}_2

(c) CH3−CH2−NO2\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NO}_2

(d) NO2−CH∣NO2−NO2{\text{N}}{{\text{O}}_{\text{2}}} - \mathop {{\text{CH}}}\limits_{\begin{array}{cccccccccccccccccccc} | \\ {{\text{N}}{{\text{O}}_{\text{2}}}} \end{array}} - {\text{N}}{{\text{O}}_{\text{2}}}
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Correct option: A
(d) >> (b) >> (a) >> ( c)
Option A ((d) >> (b) >> (a) >> ( c)) is correct because the acidity increases with the number of electron-withdrawing nitro groups attached to the carbon chain.

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